When you add a motion to a character and wish to add a second one you need to open the Timeline and place the cursor at the end of the first one.

Next double click on the second motion, or drag it on to the character, and it will follow the first one as shown below.

You can do this for every additional motion that you want to add by making sure that you scrub to the end of the previously added one first.
Gerry
System: Win 10 Pro (21H2), Asus X99-E WS, CPU i7-5930K -3,5 GHz, 32 GB DDR4 2666-16 RAM, NVidia GTX 1080 Ti GPU - 11 GB VRAM(Driver Studio-536.99), Samsung 850 Pro 512 GB SSD, 6 TB HD storage.