In CrazyTalk Animator 3 G3 characters come with both front and side view characters. You can find sample characters and a template character under Actor > Character > 1_G3 Human.
In addition, G2 characters support multiple angles so you can have a full side view in the 90-degree or 270-degree angle like in your example.
Once you create a character using either G3 or G2 as the base, you will be able to fully animate them.
If you are using Crazytalk Animator 3 Pipeline you have the option of using the PSD templates which will allow you to create your characters in Photoshop or another image editor that supports PSD files. If you are using the Pro version then you can create the character from within CTA3 itself.
You can find tutorials on creating G3 characters HERE
and G2 characters HERE